Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate

In the title hydrated salt, (C(5)H(14)N(2))(2)[Bi(2)Br(10)]·2H(2)O, the com­plete [Bi(2)Br(10)](4−) biocta­hedron is generated by crystallographic inversion symmetry. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. In the crystal,...

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Detalles Bibliográficos
Autores principales: Essid, Manel, Roisnel, Thierry, Marouani, Houda
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051086/
https://www.ncbi.nlm.nih.gov/pubmed/24940195
http://dx.doi.org/10.1107/S1600536814009805
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author Essid, Manel
Roisnel, Thierry
Marouani, Houda
author_facet Essid, Manel
Roisnel, Thierry
Marouani, Houda
author_sort Essid, Manel
collection PubMed
description In the title hydrated salt, (C(5)H(14)N(2))(2)[Bi(2)Br(10)]·2H(2)O, the com­plete [Bi(2)Br(10)](4−) biocta­hedron is generated by crystallographic inversion symmetry. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. In the crystal, the tetra­anions and water mol­ecules are linked by O—H⋯Br and O—H⋯(Br,Br) hydrogen bonds to generate [100] chains. The chains are crosslinked by N—H⋯Br, N—H⋯O and C—H⋯Br hydrogen bonds originating from the piperazinediium dications, thereby forming a three-dimensional network.
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spelling pubmed-40510862014-06-17 Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate Essid, Manel Roisnel, Thierry Marouani, Houda Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title hydrated salt, (C(5)H(14)N(2))(2)[Bi(2)Br(10)]·2H(2)O, the com­plete [Bi(2)Br(10)](4−) biocta­hedron is generated by crystallographic inversion symmetry. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. In the crystal, the tetra­anions and water mol­ecules are linked by O—H⋯Br and O—H⋯(Br,Br) hydrogen bonds to generate [100] chains. The chains are crosslinked by N—H⋯Br, N—H⋯O and C—H⋯Br hydrogen bonds originating from the piperazinediium dications, thereby forming a three-dimensional network. International Union of Crystallography 2014-05-10 /pmc/articles/PMC4051086/ /pubmed/24940195 http://dx.doi.org/10.1107/S1600536814009805 Text en © Essid et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Essid, Manel
Roisnel, Thierry
Marouani, Houda
Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title_full Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title_fullStr Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title_full_unstemmed Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title_short Bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(III)] dihydrate
title_sort bis(1-methyl­piperazine-1,4-diium) di-μ-bromido-bis­[tetra­bromido­bismuthate(iii)] dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051086/
https://www.ncbi.nlm.nih.gov/pubmed/24940195
http://dx.doi.org/10.1107/S1600536814009805
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AT marouanihouda bis1methylpiperazine14diiumdimbromidobistetrabromidobismuthateiiidihydrate

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