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Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2) N,N′}aniline)mercury(II)
In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetrahedral, comprising two Cl atoms [Hg—C...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051090/ https://www.ncbi.nlm.nih.gov/pubmed/24940192 http://dx.doi.org/10.1107/S160053681400957X |
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author | Faizi, Md. Serajul Haque Hussain, Sahid |
author_facet | Faizi, Md. Serajul Haque Hussain, Sahid |
author_sort | Faizi, Md. Serajul Haque |
collection | PubMed |
description | In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H⋯Cl hydrogen bonds and weak π–π aromatic ring stacking interactions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network. |
format | Online Article Text |
id | pubmed-4051090 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510902014-06-17 Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2) N,N′}aniline)mercury(II) Faizi, Md. Serajul Haque Hussain, Sahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-ylmethylidene)benzene-1,4-diamine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetrahedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H⋯Cl hydrogen bonds and weak π–π aromatic ring stacking interactions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network. International Union of Crystallography 2014-05-03 /pmc/articles/PMC4051090/ /pubmed/24940192 http://dx.doi.org/10.1107/S160053681400957X Text en © Faizi and Hussain 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Faizi, Md. Serajul Haque Hussain, Sahid Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2) N,N′}aniline)mercury(II) |
title | Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
N,N′}aniline)mercury(II) |
title_full | Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
N,N′}aniline)mercury(II) |
title_fullStr | Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
N,N′}aniline)mercury(II) |
title_full_unstemmed | Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
N,N′}aniline)mercury(II) |
title_short | Dichlorido(N,N-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
N,N′}aniline)mercury(II) |
title_sort | dichlorido(n,n-diethyl-4-{[(quinolin-2-yl)methylidene]amino-κ(2)
n,n′}aniline)mercury(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051090/ https://www.ncbi.nlm.nih.gov/pubmed/24940192 http://dx.doi.org/10.1107/S160053681400957X |
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