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Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)

In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-yl­methyl­idene)benzene-1,4-di­amine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetra­hedral, comprising two Cl atoms [Hg—C...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Hussain, Sahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051090/
https://www.ncbi.nlm.nih.gov/pubmed/24940192
http://dx.doi.org/10.1107/S160053681400957X
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author Faizi, Md. Serajul Haque
Hussain, Sahid
author_facet Faizi, Md. Serajul Haque
Hussain, Sahid
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-yl­methyl­idene)benzene-1,4-di­amine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H⋯Cl hydrogen bonds and weak π–π aromatic ring stacking inter­actions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network.
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spelling pubmed-40510902014-06-17 Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II) Faizi, Md. Serajul Haque Hussain, Sahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [HgCl(2)(C(20)H(21)N(3))], synthesized from the quinoline-derived Schiff base N (1),N (1)-diethyl-N (4)-(quinolin-2-yl­methyl­idene)benzene-1,4-di­amine (QMBD), the coordination geometry around the Hg(2+) atom is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H⋯Cl hydrogen bonds and weak π–π aromatic ring stacking inter­actions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network. International Union of Crystallography 2014-05-03 /pmc/articles/PMC4051090/ /pubmed/24940192 http://dx.doi.org/10.1107/S160053681400957X Text en © Faizi and Hussain 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Faizi, Md. Serajul Haque
Hussain, Sahid
Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title_full Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title_fullStr Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title_full_unstemmed Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title_short Di­chlorido­(N,N-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) N,N′}aniline)mercury(II)
title_sort di­chlorido­(n,n-diethyl-4-{[(quinolin-2-yl)methyl­idene]amino-κ(2) n,n′}aniline)mercury(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051090/
https://www.ncbi.nlm.nih.gov/pubmed/24940192
http://dx.doi.org/10.1107/S160053681400957X
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