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2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate

The mol­ecule of the title compound, C(9)H(7)IN(4)OS, is almost planar (r.m.s. deviation = 0.0373 Å). In the mol­ecule, N—H⋯N and N—H⋯O hydrogen bonds generate, respectively, S(5) and S(6) ring motifs. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds, forming chains propagating along [...

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Autores principales: Conceição Duarte de Bittencourt, Viviane, Carratu Gervini, Vanessa, Rosa de Menezes Vicenti, Juliano, Maciel Velasques, Jecika, Jussiane Zambiazi, Priscilla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051098/
https://www.ncbi.nlm.nih.gov/pubmed/24940248
http://dx.doi.org/10.1107/S1600536814010782
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author Conceição Duarte de Bittencourt, Viviane
Carratu Gervini, Vanessa
Rosa de Menezes Vicenti, Juliano
Maciel Velasques, Jecika
Jussiane Zambiazi, Priscilla
author_facet Conceição Duarte de Bittencourt, Viviane
Carratu Gervini, Vanessa
Rosa de Menezes Vicenti, Juliano
Maciel Velasques, Jecika
Jussiane Zambiazi, Priscilla
author_sort Conceição Duarte de Bittencourt, Viviane
collection PubMed
description The mol­ecule of the title compound, C(9)H(7)IN(4)OS, is almost planar (r.m.s. deviation = 0.0373 Å). In the mol­ecule, N—H⋯N and N—H⋯O hydrogen bonds generate, respectively, S(5) and S(6) ring motifs. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds, forming chains propagating along [010]. These chains are linked via S⋯I contacts [3.4915 (16) Å], forming sheets lying parallel to (100). A region of disordered electron density, probably a disordered tetra­hydro­furan solvent mol­ecule, was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The formula mass and unit-cell characteristics were not taken into account during refinement.
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spelling pubmed-40510982014-06-17 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate Conceição Duarte de Bittencourt, Viviane Carratu Gervini, Vanessa Rosa de Menezes Vicenti, Juliano Maciel Velasques, Jecika Jussiane Zambiazi, Priscilla Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(9)H(7)IN(4)OS, is almost planar (r.m.s. deviation = 0.0373 Å). In the mol­ecule, N—H⋯N and N—H⋯O hydrogen bonds generate, respectively, S(5) and S(6) ring motifs. In the crystal, mol­ecules are linked via N—H⋯O hydrogen bonds, forming chains propagating along [010]. These chains are linked via S⋯I contacts [3.4915 (16) Å], forming sheets lying parallel to (100). A region of disordered electron density, probably a disordered tetra­hydro­furan solvent mol­ecule, was treated using the SQUEEZE routine in PLATON [Spek (2009). Acta Cryst. D65, 148–155]. The formula mass and unit-cell characteristics were not taken into account during refinement. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051098/ /pubmed/24940248 http://dx.doi.org/10.1107/S1600536814010782 Text en © Conceição Duarte de Bittencourt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Conceição Duarte de Bittencourt, Viviane
Carratu Gervini, Vanessa
Rosa de Menezes Vicenti, Juliano
Maciel Velasques, Jecika
Jussiane Zambiazi, Priscilla
2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title_full 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title_fullStr 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title_full_unstemmed 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title_short 2-(5-Iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
title_sort 2-(5-iodo-2-oxoindolin-3-yl­idene)hydrazinecarbo­thio­amide including an unknown solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051098/
https://www.ncbi.nlm.nih.gov/pubmed/24940248
http://dx.doi.org/10.1107/S1600536814010782
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