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4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione

The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hy­droxy­benzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hy­droxy group and the triazole ring in concert with weak N—H⋯S inter­molecular inter­actions...

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Autores principales: Sarojini, Balladka K., Manjula, Padmanabha S., Narayana, B., Jasinski, Jerry P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051099/
https://www.ncbi.nlm.nih.gov/pubmed/24940299
http://dx.doi.org/10.1107/S1600536814012215
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author Sarojini, Balladka K.
Manjula, Padmanabha S.
Narayana, B.
Jasinski, Jerry P.
author_facet Sarojini, Balladka K.
Manjula, Padmanabha S.
Narayana, B.
Jasinski, Jerry P.
author_sort Sarojini, Balladka K.
collection PubMed
description The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hy­droxy­benzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hy­droxy group and the triazole ring in concert with weak N—H⋯S inter­molecular inter­actions between the triazole ring and thione group form chains along [-210] enclosing R (2) (2)(8) graph-set motifs. A weak intra­molecular C—H⋯S inter­action and inter­molecular π–π inter­actions [centroid–centroid distance = 3.5990 (15) Å] are also observed.
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spelling pubmed-40510992014-06-17 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione Sarojini, Balladka K. Manjula, Padmanabha S. Narayana, B. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hy­droxy­benzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hy­droxy group and the triazole ring in concert with weak N—H⋯S inter­molecular inter­actions between the triazole ring and thione group form chains along [-210] enclosing R (2) (2)(8) graph-set motifs. A weak intra­molecular C—H⋯S inter­action and inter­molecular π–π inter­actions [centroid–centroid distance = 3.5990 (15) Å] are also observed. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051099/ /pubmed/24940299 http://dx.doi.org/10.1107/S1600536814012215 Text en © Sarojini et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sarojini, Balladka K.
Manjula, Padmanabha S.
Narayana, B.
Jasinski, Jerry P.
4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_short 4-[(E)-(4-Hy­droxy­benzyl­idene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-[(e)-(4-hy­droxy­benzyl­idene)amino]-3-methyl-1h-1,2,4-triazole-5(4h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051099/
https://www.ncbi.nlm.nih.gov/pubmed/24940299
http://dx.doi.org/10.1107/S1600536814012215
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