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4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione
The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hydroxybenzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hydroxy group and the triazole ring in concert with weak N—H⋯S intermolecular interactions...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051099/ https://www.ncbi.nlm.nih.gov/pubmed/24940299 http://dx.doi.org/10.1107/S1600536814012215 |
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author | Sarojini, Balladka K. Manjula, Padmanabha S. Narayana, B. Jasinski, Jerry P. |
author_facet | Sarojini, Balladka K. Manjula, Padmanabha S. Narayana, B. Jasinski, Jerry P. |
author_sort | Sarojini, Balladka K. |
collection | PubMed |
description | The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hydroxybenzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hydroxy group and the triazole ring in concert with weak N—H⋯S intermolecular interactions between the triazole ring and thione group form chains along [-210] enclosing R (2) (2)(8) graph-set motifs. A weak intramolecular C—H⋯S interaction and intermolecular π–π interactions [centroid–centroid distance = 3.5990 (15) Å] are also observed. |
format | Online Article Text |
id | pubmed-4051099 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40510992014-06-17 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione Sarojini, Balladka K. Manjula, Padmanabha S. Narayana, B. Jasinski, Jerry P. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(10)N(4)OS, is nearly planar with the mean planes of the hydroxybenzyl and triazole rings inclined at an angle of only 3.2 (7)°. In the crystal, O—H⋯N hydrogen bonds between the hydroxy group and the triazole ring in concert with weak N—H⋯S intermolecular interactions between the triazole ring and thione group form chains along [-210] enclosing R (2) (2)(8) graph-set motifs. A weak intramolecular C—H⋯S interaction and intermolecular π–π interactions [centroid–centroid distance = 3.5990 (15) Å] are also observed. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051099/ /pubmed/24940299 http://dx.doi.org/10.1107/S1600536814012215 Text en © Sarojini et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sarojini, Balladka K. Manjula, Padmanabha S. Narayana, B. Jasinski, Jerry P. 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title | 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title_full | 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title_fullStr | 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title_full_unstemmed | 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title_short | 4-[(E)-(4-Hydroxybenzylidene)amino]-3-methyl-1H-1,2,4-triazole-5(4H)-thione |
title_sort | 4-[(e)-(4-hydroxybenzylidene)amino]-3-methyl-1h-1,2,4-triazole-5(4h)-thione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051099/ https://www.ncbi.nlm.nih.gov/pubmed/24940299 http://dx.doi.org/10.1107/S1600536814012215 |
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