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(Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I)
In the mononuclear title complex, [CuI(CH(3)CN)(C(18)H(15)P)(2)], the Cu(I) ion is in a distorted tetrahedral geometry, coordinated by two P atoms of two triphenylphosphane ligands, one N atom of an acetonitrile ligand and one iodide anion. The acetonitrile ligand is disordered over two sets of...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051102/ https://www.ncbi.nlm.nih.gov/pubmed/24940205 http://dx.doi.org/10.1107/S1600536814010940 |
| _version_ | 1782320059876638720 |
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| author | Wattanakanjana, Yupa Nimthong, Arunpatcha Mokakul, Jedsada Sukpornsawan, Phattarin |
| author_facet | Wattanakanjana, Yupa Nimthong, Arunpatcha Mokakul, Jedsada Sukpornsawan, Phattarin |
| author_sort | Wattanakanjana, Yupa |
| collection | PubMed |
| description | In the mononuclear title complex, [CuI(CH(3)CN)(C(18)H(15)P)(2)], the Cu(I) ion is in a distorted tetrahedral geometry, coordinated by two P atoms of two triphenylphosphane ligands, one N atom of an acetonitrile ligand and one iodide anion. The acetonitrile ligand is disordered over two sets of sites in a 0.629 (15): 0.371 (15) ratio. In the crystal, weak C—H⋯I hydrogen bonds link the molecules, forming a chain along [100]. |
| format | Online Article Text |
| id | pubmed-4051102 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40511022014-06-17 (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) Wattanakanjana, Yupa Nimthong, Arunpatcha Mokakul, Jedsada Sukpornsawan, Phattarin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [CuI(CH(3)CN)(C(18)H(15)P)(2)], the Cu(I) ion is in a distorted tetrahedral geometry, coordinated by two P atoms of two triphenylphosphane ligands, one N atom of an acetonitrile ligand and one iodide anion. The acetonitrile ligand is disordered over two sets of sites in a 0.629 (15): 0.371 (15) ratio. In the crystal, weak C—H⋯I hydrogen bonds link the molecules, forming a chain along [100]. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051102/ /pubmed/24940205 http://dx.doi.org/10.1107/S1600536814010940 Text en © Wattanakanjana et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wattanakanjana, Yupa Nimthong, Arunpatcha Mokakul, Jedsada Sukpornsawan, Phattarin (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title | (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title_full | (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title_fullStr | (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title_full_unstemmed | (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title_short | (Acetonitrile-κN)iodidobis(triphenylphosphane-κP)copper(I) |
| title_sort | (acetonitrile-κn)iodidobis(triphenylphosphane-κp)copper(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051102/ https://www.ncbi.nlm.nih.gov/pubmed/24940205 http://dx.doi.org/10.1107/S1600536814010940 |
| work_keys_str_mv | AT wattanakanjanayupa acetonitrilekniodidobistriphenylphosphanekpcopperi AT nimthongarunpatcha acetonitrilekniodidobistriphenylphosphanekpcopperi AT mokakuljedsada acetonitrilekniodidobistriphenylphosphanekpcopperi AT sukpornsawanphattarin acetonitrilekniodidobistriphenylphosphanekpcopperi |