Cs(5)Sn(9)(OH)·4NH(3)

The title compound, penta­caesium nona­stannide hydroxide tetra­ammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn(9) (4−) unit forms a monocapped quadratic anti­prism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedr...

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Detalles Bibliográficos
Autores principales: Friedrich, Ute, Korber, Nikolaus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051103/
https://www.ncbi.nlm.nih.gov/pubmed/24940189
http://dx.doi.org/10.1107/S1600536814011817
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author Friedrich, Ute
Korber, Nikolaus
author_facet Friedrich, Ute
Korber, Nikolaus
author_sort Friedrich, Ute
collection PubMed
description The title compound, penta­caesium nona­stannide hydroxide tetra­ammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn(9) (4−) unit forms a monocapped quadratic anti­prism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs—Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs—NH(3) [3.276 (7)–3.636 (7) Å] contacts.
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spelling pubmed-40511032014-06-17 Cs(5)Sn(9)(OH)·4NH(3) Friedrich, Ute Korber, Nikolaus Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, penta­caesium nona­stannide hydroxide tetra­ammonia, crystallized from a solution of CsSnBi in liquid ammonia. The Sn(9) (4−) unit forms a monocapped quadratic anti­prism. The hydroxide ion is surrounded by five caesium cations, which form a distorted quadratic pyramidal polyhedron. A three-dimensional network is formed by Cs—Sn [3.8881 (7) Å to 4.5284 (7) Å] and Cs—NH(3) [3.276 (7)–3.636 (7) Å] contacts. International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051103/ /pubmed/24940189 http://dx.doi.org/10.1107/S1600536814011817 Text en © Friedrich and Korber 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Friedrich, Ute
Korber, Nikolaus
Cs(5)Sn(9)(OH)·4NH(3)
title Cs(5)Sn(9)(OH)·4NH(3)
title_full Cs(5)Sn(9)(OH)·4NH(3)
title_fullStr Cs(5)Sn(9)(OH)·4NH(3)
title_full_unstemmed Cs(5)Sn(9)(OH)·4NH(3)
title_short Cs(5)Sn(9)(OH)·4NH(3)
title_sort cs(5)sn(9)(oh)·4nh(3)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051103/
https://www.ncbi.nlm.nih.gov/pubmed/24940189
http://dx.doi.org/10.1107/S1600536814011817
work_keys_str_mv AT friedrichute cs5sn9oh4nh3
AT korbernikolaus cs5sn9oh4nh3

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