Cargando…
catena-Poly[[bis(pyridine-κN)nickel(II)]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N]
In the title compound, [Ni(NCS)(2)(C(5)H(5)N)(2)](n), the Ni(2+) cation is coordinated by four thiocyanate anions (μ-1,3) and two pyridine ligands within a slightly distorted octahedral configuration. The Ni—N bond lengths to the pyridine rings are 2.1189 (17) and 2.1241 (17) Å, whereas those to t...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051106/ https://www.ncbi.nlm.nih.gov/pubmed/24940191 http://dx.doi.org/10.1107/S1600536814009611 |
| Sumario: | In the title compound, [Ni(NCS)(2)(C(5)H(5)N)(2)](n), the Ni(2+) cation is coordinated by four thiocyanate anions (μ-1,3) and two pyridine ligands within a slightly distorted octahedral configuration. The Ni—N bond lengths to the pyridine rings are 2.1189 (17) and 2.1241 (17) Å, whereas those to the thiocyanate anions are 2.0299 (18) and 2.0359 Å. The Ni—S bond lengths are 2.5357 (6) and 2.5568 (6) Å. The Ni(2+) cations are linked by N:S-bridging thiocyanate ligands into chains extending along [010]. The Ni⋯Ni distance within the chains is 5.5820 (5) Å. The asymmetric unit contains two Ni(2+) cations of which one is located on a centre of inversion, whereas the second is located on a general position. |
|---|