Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate

The complete mol­ecule of the title compound, C(24)H(28)N(4)O(4), is generated by crystallographic inversion symmetry. The ethyl side chain is disordered over two sets of sites in a 0.57 (4):0.43 (4) ratio. The dihedral angles between the methyl­idene group and the phenyl ring and ester side chain (...

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Detalles Bibliográficos
Autores principales: Liu, Peng, Yuan, Libin, Song, Xiuqing, Yan, Hong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051109/
https://www.ncbi.nlm.nih.gov/pubmed/24940292
http://dx.doi.org/10.1107/S1600536814011970
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author Liu, Peng
Yuan, Libin
Song, Xiuqing
Yan, Hong
author_facet Liu, Peng
Yuan, Libin
Song, Xiuqing
Yan, Hong
author_sort Liu, Peng
collection PubMed
description The complete mol­ecule of the title compound, C(24)H(28)N(4)O(4), is generated by crystallographic inversion symmetry. The ethyl side chain is disordered over two sets of sites in a 0.57 (4):0.43 (4) ratio. The dihedral angles between the methyl­idene group and the phenyl ring and ester side chain (major conformation) are 7.61 (8) and 86.95 (8)°, respectively. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming corrugated sheets lying parallel to (010).
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spelling pubmed-40511092014-06-17 Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate Liu, Peng Yuan, Libin Song, Xiuqing Yan, Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers The complete mol­ecule of the title compound, C(24)H(28)N(4)O(4), is generated by crystallographic inversion symmetry. The ethyl side chain is disordered over two sets of sites in a 0.57 (4):0.43 (4) ratio. The dihedral angles between the methyl­idene group and the phenyl ring and ester side chain (major conformation) are 7.61 (8) and 86.95 (8)°, respectively. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming corrugated sheets lying parallel to (010). International Union of Crystallography 2014-05-31 /pmc/articles/PMC4051109/ /pubmed/24940292 http://dx.doi.org/10.1107/S1600536814011970 Text en © Liu et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Peng
Yuan, Libin
Song, Xiuqing
Yan, Hong
Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title_full Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title_fullStr Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title_full_unstemmed Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title_short Diethyl (E)-2,3-bis­[(E)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
title_sort diethyl (e)-2,3-bis­[(e)-(2-methyl-2-phenyl­hydrazin-1-yl­idene)meth­yl]but-2-enedioate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051109/
https://www.ncbi.nlm.nih.gov/pubmed/24940292
http://dx.doi.org/10.1107/S1600536814011970
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