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N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide
In the title compound, C(12)H(8)BrClN(2)O(3), the furan ring makes a dihedral angle of 17.2 (2)° with the six-membered ring. An intramolecular O–H⋯N hydrogen bond stabilizes the molecular conformation. In the crystal, N–H⋯O hydrogen bonds connect the molecules into chains running along the c-axis...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051112/ https://www.ncbi.nlm.nih.gov/pubmed/24940251 http://dx.doi.org/10.1107/S160053681401085X |
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author | Sundar, A. Ranjith, S. Rajagopal, G. |
author_facet | Sundar, A. Ranjith, S. Rajagopal, G. |
author_sort | Sundar, A. |
collection | PubMed |
description | In the title compound, C(12)H(8)BrClN(2)O(3), the furan ring makes a dihedral angle of 17.2 (2)° with the six-membered ring. An intramolecular O–H⋯N hydrogen bond stabilizes the molecular conformation. In the crystal, N–H⋯O hydrogen bonds connect the molecules into chains running along the c-axis direction. The crystal packing is additionally stabilized by C—H⋯O interactions into a three-dimensional supramolecular architecture. |
format | Online Article Text |
id | pubmed-4051112 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40511122014-06-17 N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide Sundar, A. Ranjith, S. Rajagopal, G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(12)H(8)BrClN(2)O(3), the furan ring makes a dihedral angle of 17.2 (2)° with the six-membered ring. An intramolecular O–H⋯N hydrogen bond stabilizes the molecular conformation. In the crystal, N–H⋯O hydrogen bonds connect the molecules into chains running along the c-axis direction. The crystal packing is additionally stabilized by C—H⋯O interactions into a three-dimensional supramolecular architecture. International Union of Crystallography 2014-05-17 /pmc/articles/PMC4051112/ /pubmed/24940251 http://dx.doi.org/10.1107/S160053681401085X Text en © Sundar et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sundar, A. Ranjith, S. Rajagopal, G. N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title |
N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title_full |
N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title_fullStr |
N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title_full_unstemmed |
N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title_short |
N′-[(E)-3-Bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
title_sort | n′-[(e)-3-bromo-5-chloro-2-hydroxybenzylidene]furan-2-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051112/ https://www.ncbi.nlm.nih.gov/pubmed/24940251 http://dx.doi.org/10.1107/S160053681401085X |
work_keys_str_mv | AT sundara ne3bromo5chloro2hydroxybenzylidenefuran2carbohydrazide AT ranjiths ne3bromo5chloro2hydroxybenzylidenefuran2carbohydrazide AT rajagopalg ne3bromo5chloro2hydroxybenzylidenefuran2carbohydrazide |