La(3)Si(6)N(11)

Colorless transparent single crystals of trilanthanum hexa­silicon undeca­nitro­gen, La(3)Si(6)N(11), were prepared at 0.85 MPa of N(2) and 2273 K. The title compound is isotypic with Sm(3)Si(6)N(11). Silicon-centered nitro­gen tetra­hedra form a three-dimensional network structure by sharing their...

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Detalles Bibliográficos
Autores principales: Yamane, Hisanori, Nagura, Toshiki, Miyazaki, Tomohiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051113/
https://www.ncbi.nlm.nih.gov/pubmed/24940184
http://dx.doi.org/10.1107/S1600536814009234
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author Yamane, Hisanori
Nagura, Toshiki
Miyazaki, Tomohiro
author_facet Yamane, Hisanori
Nagura, Toshiki
Miyazaki, Tomohiro
author_sort Yamane, Hisanori
collection PubMed
description Colorless transparent single crystals of trilanthanum hexa­silicon undeca­nitro­gen, La(3)Si(6)N(11), were prepared at 0.85 MPa of N(2) and 2273 K. The title compound is isotypic with Sm(3)Si(6)N(11). Silicon-centered nitro­gen tetra­hedra form a three-dimensional network structure by sharing their corners. Layers of one type of SiN(4) tetra­hedra and slabs composed of the two different La(3+) cations and the other type of SiN(4) tetra­hedra are alternately stacked along the c axis of the tetra­gonal unit cell. The site symmetries of the two La(3+) cations are are ..m and 4.., respectively.
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spelling pubmed-40511132014-06-17 La(3)Si(6)N(11) Yamane, Hisanori Nagura, Toshiki Miyazaki, Tomohiro Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Colorless transparent single crystals of trilanthanum hexa­silicon undeca­nitro­gen, La(3)Si(6)N(11), were prepared at 0.85 MPa of N(2) and 2273 K. The title compound is isotypic with Sm(3)Si(6)N(11). Silicon-centered nitro­gen tetra­hedra form a three-dimensional network structure by sharing their corners. Layers of one type of SiN(4) tetra­hedra and slabs composed of the two different La(3+) cations and the other type of SiN(4) tetra­hedra are alternately stacked along the c axis of the tetra­gonal unit cell. The site symmetries of the two La(3+) cations are are ..m and 4.., respectively. International Union of Crystallography 2014-05-03 /pmc/articles/PMC4051113/ /pubmed/24940184 http://dx.doi.org/10.1107/S1600536814009234 Text en © Yamane et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Yamane, Hisanori
Nagura, Toshiki
Miyazaki, Tomohiro
La(3)Si(6)N(11)
title La(3)Si(6)N(11)
title_full La(3)Si(6)N(11)
title_fullStr La(3)Si(6)N(11)
title_full_unstemmed La(3)Si(6)N(11)
title_short La(3)Si(6)N(11)
title_sort la(3)si(6)n(11)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051113/
https://www.ncbi.nlm.nih.gov/pubmed/24940184
http://dx.doi.org/10.1107/S1600536814009234
work_keys_str_mv AT yamanehisanori la3si6n11
AT naguratoshiki la3si6n11
AT miyazakitomohiro la3si6n11

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