Cargando…
2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene
The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with d...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051115/ https://www.ncbi.nlm.nih.gov/pubmed/24940272 http://dx.doi.org/10.1107/S1600536814011398 |
Sumario: | The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π interactions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å. |
---|