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2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene
The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with d...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051115/ https://www.ncbi.nlm.nih.gov/pubmed/24940272 http://dx.doi.org/10.1107/S1600536814011398 |
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author | Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang |
author_facet | Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang |
author_sort | Luo, Hai-Kun |
collection | PubMed |
description | The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π interactions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å. |
format | Online Article Text |
id | pubmed-4051115 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-40511152014-06-17 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bisthiophene-type Schiff base ligand with a perfluorinated backbone. The terminal thiophene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetrafluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π interactions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051115/ /pubmed/24940272 http://dx.doi.org/10.1107/S1600536814011398 Text en © Luo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title | 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title_full | 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title_fullStr | 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title_full_unstemmed | 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title_short | 2,3,5,6-Tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
title_sort | 2,3,5,6-tetrafluoro-1,4-bis({[(5-methylthiophen-2-yl)methylidene]amino}methyl)benzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051115/ https://www.ncbi.nlm.nih.gov/pubmed/24940272 http://dx.doi.org/10.1107/S1600536814011398 |
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