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2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene

The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bis­thio­phene-type Schiff base ligand with a perfluorinated backbone. The terminal thio­phene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetra­fluorinated benzene ring with d...

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Detalles Bibliográficos
Autores principales: Luo, Hai-Kun, Qin, Rui-Rui, He, Ming-Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051115/
https://www.ncbi.nlm.nih.gov/pubmed/24940272
http://dx.doi.org/10.1107/S1600536814011398
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author Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
author_facet Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
author_sort Luo, Hai-Kun
collection PubMed
description The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bis­thio­phene-type Schiff base ligand with a perfluorinated backbone. The terminal thio­phene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetra­fluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π inter­actions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å.
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spelling pubmed-40511152014-06-17 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene Luo, Hai-Kun Qin, Rui-Rui He, Ming-Yang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(16)F(4)N(2)S(2), is a flexible bis­thio­phene-type Schiff base ligand with a perfluorinated backbone. The terminal thio­phene rings are almost normal to one another with a dihedral angle of 83.8 (2)°, and they are tilted to the central tetra­fluorinated benzene ring with dihedral angles of 61.2 (2) and 77.7 (1)°. In the crystal, there are π–π inter­actions involving the benzene ring and the thiophene ring of a symmetry-related molecule with a centroid–centroid separation of 3.699 (3) Å. International Union of Crystallography 2014-05-24 /pmc/articles/PMC4051115/ /pubmed/24940272 http://dx.doi.org/10.1107/S1600536814011398 Text en © Luo et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Luo, Hai-Kun
Qin, Rui-Rui
He, Ming-Yang
2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_full 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_fullStr 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_full_unstemmed 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_short 2,3,5,6-Tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
title_sort 2,3,5,6-tetra­fluoro-1,4-bis­({[(5-methyl­thio­phen-2-yl)methyl­idene]amino}­meth­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4051115/
https://www.ncbi.nlm.nih.gov/pubmed/24940272
http://dx.doi.org/10.1107/S1600536814011398
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AT qinruirui 2356tetrafluoro14bis5methylthiophen2ylmethylideneaminomethylbenzene
AT hemingyang 2356tetrafluoro14bis5methylthiophen2ylmethylideneaminomethylbenzene