Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling

In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (Pyr(14)TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance...

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Detalles Bibliográficos
Autores principales: Grande, Lorenzo, Paillard, Elie, Kim, Guk-Tae, Monaco, Simone, Passerini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International (MDPI) 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4057723/
https://www.ncbi.nlm.nih.gov/pubmed/24815072
http://dx.doi.org/10.3390/ijms15058122
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author Grande, Lorenzo
Paillard, Elie
Kim, Guk-Tae
Monaco, Simone
Passerini, Stefano
author_facet Grande, Lorenzo
Paillard, Elie
Kim, Guk-Tae
Monaco, Simone
Passerini, Stefano
author_sort Grande, Lorenzo
collection PubMed
description In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (Pyr(14)TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance spectroscopy measurements and galvanostatic cycling at different temperatures are performed to analyze the influence of temperature on the stabilization of the solid electrolyte interphase (SEI), showing that TFSI-based ionic liquids (ILs) rank among the best candidates for long-lasting Li–air cells.
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spelling pubmed-40577232014-06-16 Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling Grande, Lorenzo Paillard, Elie Kim, Guk-Tae Monaco, Simone Passerini, Stefano Int J Mol Sci Article In this work, the electrochemical stability and lithium plating/stripping performance of N-butyl-N-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (Pyr(14)TFSI) are reported, by investigating the behavior of Li metal electrodes in symmetrical Li/electrolyte/Li cells. Electrochemical impedance spectroscopy measurements and galvanostatic cycling at different temperatures are performed to analyze the influence of temperature on the stabilization of the solid electrolyte interphase (SEI), showing that TFSI-based ionic liquids (ILs) rank among the best candidates for long-lasting Li–air cells. Molecular Diversity Preservation International (MDPI) 2014-05-08 /pmc/articles/PMC4057723/ /pubmed/24815072 http://dx.doi.org/10.3390/ijms15058122 Text en © 2014 by the authors; licensee MDPI, Basel, Switzerland http://creativecommons.org/licenses/by/3.0/ This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Grande, Lorenzo
Paillard, Elie
Kim, Guk-Tae
Monaco, Simone
Passerini, Stefano
Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title_full Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title_fullStr Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title_full_unstemmed Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title_short Ionic Liquid Electrolytes for Li–Air Batteries: Lithium Metal Cycling
title_sort ionic liquid electrolytes for li–air batteries: lithium metal cycling
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4057723/
https://www.ncbi.nlm.nih.gov/pubmed/24815072
http://dx.doi.org/10.3390/ijms15058122
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AT paillardelie ionicliquidelectrolytesforliairbatterieslithiummetalcycling
AT kimguktae ionicliquidelectrolytesforliairbatterieslithiummetalcycling
AT monacosimone ionicliquidelectrolytesforliairbatterieslithiummetalcycling
AT passerinistefano ionicliquidelectrolytesforliairbatterieslithiummetalcycling

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