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Functionalization of Complexed N(2)O in Bis(pentamethylcyclopentadienyl) Systems of Zirconium and Titanium
[Image: see text] Methyl triflate reacts with the metastable azoxymetallacyclopentene complex Cp*(2)Zr(N(O)NCPhCPh), generated in situ from nitrous oxide insertion into the Zr–C bond of Cp*(2)Zr(η(2)-PhCCPh) at −78 °C, to afford the salt [Cp*(2)Zr(N(O)N(Me)CPhCPh)][O(3)SCF(3)] (1) in 48% isolated yi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4059529/ https://www.ncbi.nlm.nih.gov/pubmed/24954968 http://dx.doi.org/10.1021/om5002556 |