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Enantiospecific Intramolecular Heck Reactions of Secondary Benzylic Ethers
[Image: see text] Enantioenriched methylenecyclopentanes are synthesized by stereospecific, nickel-catalyzed Heck cyclizations of secondary benzylic ethers. The reaction proceeds in high yield and enantiospecificity for benzylic ethers of both π-extended and simple arenes. Ethers with pendant 1,2-di...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4063177/ https://www.ncbi.nlm.nih.gov/pubmed/24852707 http://dx.doi.org/10.1021/ja5026485 |