Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid

[Image: see text] The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C(6)F(5))(3) leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C(6)F(5))(3), reacts with ArO–H substrates via formal hydrogen...

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Autores principales: Baglia, Regina A., Dürr, Maximilian, Ivanović-Burmazović, Ivana, Goldberg, David P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4066901/
https://www.ncbi.nlm.nih.gov/pubmed/24873989
http://dx.doi.org/10.1021/ic500901y
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author Baglia, Regina A.
Dürr, Maximilian
Ivanović-Burmazović, Ivana
Goldberg, David P.
author_facet Baglia, Regina A.
Dürr, Maximilian
Ivanović-Burmazović, Ivana
Goldberg, David P.
author_sort Baglia, Regina A.
collection PubMed
description [Image: see text] The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C(6)F(5))(3) leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C(6)F(5))(3), reacts with ArO–H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(V)(O) starting material.
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spelling pubmed-40669012015-05-29 Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid Baglia, Regina A. Dürr, Maximilian Ivanović-Burmazović, Ivana Goldberg, David P. Inorg Chem [Image: see text] The reaction of a manganese(V)–oxo porphyrinoid complex with the Lewis acid B(C(6)F(5))(3) leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C(6)F(5))(3), reacts with ArO–H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(V)(O) starting material. American Chemical Society 2014-05-29 2014-06-16 /pmc/articles/PMC4066901/ /pubmed/24873989 http://dx.doi.org/10.1021/ic500901y Text en Copyright © 2014 American Chemical Society Open Access on 05/29/2015
spellingShingle Baglia, Regina A.
Dürr, Maximilian
Ivanović-Burmazović, Ivana
Goldberg, David P.
Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title_full Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title_fullStr Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title_full_unstemmed Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title_short Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
title_sort activation of a high-valent manganese–oxo complex by a nonmetallic lewis acid
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4066901/
https://www.ncbi.nlm.nih.gov/pubmed/24873989
http://dx.doi.org/10.1021/ic500901y
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