An Approach to the Synthesis of Functionalized Polycyclic Aromatic Hydrocarbons

The application of a new benzannulation reaction for the regiocontrolled synthesis of functionalized chrysenes is reported. The initial benzannulation and the subsequent halogen displacement reactions are both highly regiospecific, which thereby enables the regiocontrolled synthesis of a variety of...

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Detalles Bibliográficos
Autores principales: Little, Mark, Lan, He, Raftery, James, Morrison, John J, McDouall, Joseph J W, Yeates, Stephen G, Quayle, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: WILEY-VCH Verlag 2013
Materias:
Short Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4068280/
https://www.ncbi.nlm.nih.gov/pubmed/25045320
http://dx.doi.org/10.1002/ejoc.201300750
Descripción
Sumario:The application of a new benzannulation reaction for the regiocontrolled synthesis of functionalized chrysenes is reported. The initial benzannulation and the subsequent halogen displacement reactions are both highly regiospecific, which thereby enables the regiocontrolled synthesis of a variety of 4,10-disubstituted chrysenes from commercially available 1,5-dihydroxynaphthalene.

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