Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks

Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a...

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Detalles Bibliográficos
Autores principales: Rubio-Martinez, Marta, Batten, Michael P., Polyzos, Anastasios, Carey, Keri-Constanti, Mardel, James I., Lim, Kok-Seng, Hill, Matthew R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4069692/
https://www.ncbi.nlm.nih.gov/pubmed/24962145
http://dx.doi.org/10.1038/srep05443
Descripción
Sumario:Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a range of MOFs, by emulating conditions of lab-scale batch synthesis. This delivers ready synthesis of three different MOFs, with surface areas that closely match theoretical maxima, with production rates of 60 g/h at extremely high space-time yields.

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