Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks

Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a...

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Detalles Bibliográficos
Autores principales: Rubio-Martinez, Marta, Batten, Michael P., Polyzos, Anastasios, Carey, Keri-Constanti, Mardel, James I., Lim, Kok-Seng, Hill, Matthew R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4069692/
https://www.ncbi.nlm.nih.gov/pubmed/24962145
http://dx.doi.org/10.1038/srep05443
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author Rubio-Martinez, Marta
Batten, Michael P.
Polyzos, Anastasios
Carey, Keri-Constanti
Mardel, James I.
Lim, Kok-Seng
Hill, Matthew R.
author_facet Rubio-Martinez, Marta
Batten, Michael P.
Polyzos, Anastasios
Carey, Keri-Constanti
Mardel, James I.
Lim, Kok-Seng
Hill, Matthew R.
author_sort Rubio-Martinez, Marta
collection PubMed
description Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a range of MOFs, by emulating conditions of lab-scale batch synthesis. This delivers ready synthesis of three different MOFs, with surface areas that closely match theoretical maxima, with production rates of 60 g/h at extremely high space-time yields.
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spelling pubmed-40696922014-08-27 Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks Rubio-Martinez, Marta Batten, Michael P. Polyzos, Anastasios Carey, Keri-Constanti Mardel, James I. Lim, Kok-Seng Hill, Matthew R. Sci Rep Article Further deployment of Metal-Organic Frameworks in applied settings requires their ready preparation at scale. Expansion of typical batch processes can lead to unsuccessful or low quality synthesis for some systems. Here we report how continuous flow chemistry can be adapted as a versatile route to a range of MOFs, by emulating conditions of lab-scale batch synthesis. This delivers ready synthesis of three different MOFs, with surface areas that closely match theoretical maxima, with production rates of 60 g/h at extremely high space-time yields. Nature Publishing Group 2014-06-25 /pmc/articles/PMC4069692/ /pubmed/24962145 http://dx.doi.org/10.1038/srep05443 Text en Copyright © 2014, Macmillan Publishers Limited. All rights reserved http://creativecommons.org/licenses/by-nc-sa/4.0/ This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License. The images or other third party material in this article are included in the article's Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder in order to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by-nc-sa/4.0/
spellingShingle Article
Rubio-Martinez, Marta
Batten, Michael P.
Polyzos, Anastasios
Carey, Keri-Constanti
Mardel, James I.
Lim, Kok-Seng
Hill, Matthew R.
Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title_full Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title_fullStr Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title_full_unstemmed Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title_short Versatile, High Quality and Scalable Continuous Flow Production of Metal-Organic Frameworks
title_sort versatile, high quality and scalable continuous flow production of metal-organic frameworks
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4069692/
https://www.ncbi.nlm.nih.gov/pubmed/24962145
http://dx.doi.org/10.1038/srep05443
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