Sulfur K-Edge X-ray Absorption Spectroscopy and Density Functional Theory Calculations on Monooxo Mo(IV) and Bisoxo Mo(VI) Bis-dithiolenes: Insights into the Mechanism of Oxo Transfer in Sulfite Oxidase and Its Relation to the Mechanism of DMSO Reductase

[Image: see text] Sulfur K-edge X-ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations have been used to determine the electronic structures of two complexes [Mo(IV)O(bdt)(2)](2–) and [Mo(VI)O(2)(bdt)(2)](2–) (bdt = benzene-1,2-dithiolate(2−)) that relate to the reduced...

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Detalles Bibliográficos
Autores principales: Ha, Yang, Tenderholt, Adam L., Holm, Richard H., Hedman, Britt, Hodgson, Keith O., Solomon, Edward I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4073832/
https://www.ncbi.nlm.nih.gov/pubmed/24884723
http://dx.doi.org/10.1021/ja503316p

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