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Lewis Base Catalyzed, Enantioselective, Intramolecular Sulfenoamination of Olefins

[Image: see text] A method for the enantioselective, intramolecular sulfenoamination of various olefins has been developed using a chiral BINAM-based selenophosphoramide, Lewis base catalyst. Terminal and trans disubstituted alkenes afforded pyrrolidines, piperidines, and azepanes in high yields and...

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Detalles Bibliográficos
Autores principales: Denmark, Scott E., Chi, Hyung Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4073881/
https://www.ncbi.nlm.nih.gov/pubmed/24926794
http://dx.doi.org/10.1021/ja5046296