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Clean and fast cross-coupling of aryl halides in one-pot

Unsymmetrically coupled biaryls are synthesized in high yield starting from different aryl bromides and bis(pinacolato)diboron by carrying out the Miyaura borylation reaction followed by the Suzuki–Miyaura reaction in the same reaction pot over 1–2 mol % SiliaCat DPP-Pd. The SiliaCat DPP-Pd catalyst...

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Detalles Bibliográficos
Autores principales: Pandarus, Valerica, Gingras, Geneviève, Béland, François, Ciriminna, Rosaria, Pagliaro, Mario
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077365/
https://www.ncbi.nlm.nih.gov/pubmed/24991238
http://dx.doi.org/10.3762/bjoc.10.87