Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones

A new, efficient and mild method for the direct oxidation of selenides to selenones using magnesium bis(monoperoxyphthalate) hexahydrate (MMPP) has been developed. Noteworthy this transformation proceeds at room temperature, employs a cheap and safety oxidant and has a broad functional group toleran...

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Autores principales: Temperini, Andrea, Curini, Massimo, Rosati, Ornelio, Minuti, Lucio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Letter
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077369/
https://www.ncbi.nlm.nih.gov/pubmed/24991278
http://dx.doi.org/10.3762/bjoc.10.127
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author Temperini, Andrea
Curini, Massimo
Rosati, Ornelio
Minuti, Lucio
author_facet Temperini, Andrea
Curini, Massimo
Rosati, Ornelio
Minuti, Lucio
author_sort Temperini, Andrea
collection PubMed
description A new, efficient and mild method for the direct oxidation of selenides to selenones using magnesium bis(monoperoxyphthalate) hexahydrate (MMPP) has been developed. Noteworthy this transformation proceeds at room temperature, employs a cheap and safety oxidant and has a broad functional group tolerance. Moreover, the produced selenones could be useful intermediates for the synthesis of different heterocyclic compounds.
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spelling pubmed-40773692014-07-02 Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones Temperini, Andrea Curini, Massimo Rosati, Ornelio Minuti, Lucio Beilstein J Org Chem Letter A new, efficient and mild method for the direct oxidation of selenides to selenones using magnesium bis(monoperoxyphthalate) hexahydrate (MMPP) has been developed. Noteworthy this transformation proceeds at room temperature, employs a cheap and safety oxidant and has a broad functional group tolerance. Moreover, the produced selenones could be useful intermediates for the synthesis of different heterocyclic compounds. Beilstein-Institut 2014-06-02 /pmc/articles/PMC4077369/ /pubmed/24991278 http://dx.doi.org/10.3762/bjoc.10.127 Text en Copyright © 2014, Temperini et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Letter
Temperini, Andrea
Curini, Massimo
Rosati, Ornelio
Minuti, Lucio
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title_full Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title_fullStr Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title_full_unstemmed Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title_short Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
title_sort magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones
topic Letter
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077369/
https://www.ncbi.nlm.nih.gov/pubmed/24991278
http://dx.doi.org/10.3762/bjoc.10.127
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