Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes

Intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes is realized using visible light photoredox catalysis, yielding a variety of cyclic allylic amines in fair to good yields. This method exhibits significant group tolerance particularly with heterocycles. It can also be used to prep...

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Detalles Bibliográficos
Autores principales: Nguyen, Theresa H, Maity, Soumitra, Zheng, Nan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077375/
https://www.ncbi.nlm.nih.gov/pubmed/24991247
http://dx.doi.org/10.3762/bjoc.10.96
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author Nguyen, Theresa H
Maity, Soumitra
Zheng, Nan
author_facet Nguyen, Theresa H
Maity, Soumitra
Zheng, Nan
author_sort Nguyen, Theresa H
collection PubMed
description Intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes is realized using visible light photoredox catalysis, yielding a variety of cyclic allylic amines in fair to good yields. This method exhibits significant group tolerance particularly with heterocycles. It can also be used to prepare complex heterocycles such as fused indolines.
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spelling pubmed-40773752014-07-02 Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes Nguyen, Theresa H Maity, Soumitra Zheng, Nan Beilstein J Org Chem Full Research Paper Intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes is realized using visible light photoredox catalysis, yielding a variety of cyclic allylic amines in fair to good yields. This method exhibits significant group tolerance particularly with heterocycles. It can also be used to prepare complex heterocycles such as fused indolines. Beilstein-Institut 2014-04-29 /pmc/articles/PMC4077375/ /pubmed/24991247 http://dx.doi.org/10.3762/bjoc.10.96 Text en Copyright © 2014, Nguyen et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Nguyen, Theresa H
Maity, Soumitra
Zheng, Nan
Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title_full Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title_fullStr Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title_full_unstemmed Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title_short Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
title_sort visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077375/
https://www.ncbi.nlm.nih.gov/pubmed/24991247
http://dx.doi.org/10.3762/bjoc.10.96
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