Synthesis of chiral N-phosphoryl aziridines through enantioselective aziridination of alkenes with phosphoryl azide via Co(II)-based metalloradical catalysis

The Co(II) complex of a new D(2)-symmetric chiral porphyrin 3,5-DiMes-QingPhyrin, [Co(P6)], can catalyze asymmetric aziridination of alkenes with bis(2,2,2-trichloroethyl)phosphoryl azide (TcepN(3)) as a nitrene source. This new Co(II)-based metalloradical aziridination is suitable for different aro...

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Detalles Bibliográficos
Autores principales: Tao, Jingran, Jin, Li-Mei, Zhang, X Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077377/
https://www.ncbi.nlm.nih.gov/pubmed/24991280
http://dx.doi.org/10.3762/bjoc.10.129

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077377/
https://www.ncbi.nlm.nih.gov/pubmed/24991280
http://dx.doi.org/10.3762/bjoc.10.129

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