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Site-selective covalent functionalization at interior carbon atoms and on the rim of circumtrindene, a C(36)H(12) open geodesic polyarene
Circumtrindene (6, C(36)H(12)), one of the largest open geodesic polyarenes ever reported, exhibits fullerene-like reactivity at its interior carbon atoms, whereas its edge carbons react like those of planar polycyclic aromatic hydrocarbons (PAHs). The Bingel–Hirsch and Prato reactions – two traditi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Beilstein-Institut
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077463/ https://www.ncbi.nlm.nih.gov/pubmed/24991245 http://dx.doi.org/10.3762/bjoc.10.94 |