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Synthesis of 1-[bis(trifluoromethyl)phosphine]-1’-oxazolinylferrocene ligands and their application in regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl substrates

A class of novel, easily accessible and air-stable 1-[bis(trifluoromethyl)phosphine]-1’-oxazolinylferrocene ligands has been synthesized from ferrocene. It became apparent that these ligands can be used in the regio- and enantioselective Pd-catalyzed allylic alkylation of monosubstituted allyl subst...

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Detalles Bibliográficos
Autores principales: Lai, Zeng-Wei, Yang, Rong-Fei, Ye, Ke-Yin, Sun, Hongbin, You, Shu-Li
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077528/
https://www.ncbi.nlm.nih.gov/pubmed/24991277
http://dx.doi.org/10.3762/bjoc.10.126