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Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol
We herein describe an environmentally friendly microwave-assisted oxidative esterification of alcohols and aldehydes in the presence of molecular oxygen and a heterogeneous catalysis (Pd/C, 5 mol %). This efficient and ligandless conversion procedure does not require the addition of an organic hydrog...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077537/ https://www.ncbi.nlm.nih.gov/pubmed/24991300 http://dx.doi.org/10.3762/bjoc.10.149 |
| _version_ | 1782323610372800512 |
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| author | Caporaso, Marina Cravotto, Giancarlo Georgakopoulos, Spyros Heropoulos, George Martina, Katia Tagliapietra, Silvia |
| author_facet | Caporaso, Marina Cravotto, Giancarlo Georgakopoulos, Spyros Heropoulos, George Martina, Katia Tagliapietra, Silvia |
| author_sort | Caporaso, Marina |
| collection | PubMed |
| description | We herein describe an environmentally friendly microwave-assisted oxidative esterification of alcohols and aldehydes in the presence of molecular oxygen and a heterogeneous catalysis (Pd/C, 5 mol %). This efficient and ligandless conversion procedure does not require the addition of an organic hydrogen acceptor. The reaction rate is strongly enhanced by mild dielectric heating. Furthermore, it is a versatile green procedure which generally enables the isolation of esters to be carried out by simple filtration in almost quantitative yields. |
| format | Online Article Text |
| id | pubmed-4077537 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | Beilstein-Institut |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-40775372014-07-02 Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol Caporaso, Marina Cravotto, Giancarlo Georgakopoulos, Spyros Heropoulos, George Martina, Katia Tagliapietra, Silvia Beilstein J Org Chem Full Research Paper We herein describe an environmentally friendly microwave-assisted oxidative esterification of alcohols and aldehydes in the presence of molecular oxygen and a heterogeneous catalysis (Pd/C, 5 mol %). This efficient and ligandless conversion procedure does not require the addition of an organic hydrogen acceptor. The reaction rate is strongly enhanced by mild dielectric heating. Furthermore, it is a versatile green procedure which generally enables the isolation of esters to be carried out by simple filtration in almost quantitative yields. Beilstein-Institut 2014-06-26 /pmc/articles/PMC4077537/ /pubmed/24991300 http://dx.doi.org/10.3762/bjoc.10.149 Text en Copyright © 2014, Caporaso et al. https://creativecommons.org/licenses/by/2.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms) |
| spellingShingle | Full Research Paper Caporaso, Marina Cravotto, Giancarlo Georgakopoulos, Spyros Heropoulos, George Martina, Katia Tagliapietra, Silvia Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title | Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title_full | Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title_fullStr | Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title_full_unstemmed | Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title_short | Pd/C-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| title_sort | pd/c-catalyzed aerobic oxidative esterification of alcohols and aldehydes: a highly efficient microwave-assisted green protocol |
| topic | Full Research Paper |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4077537/ https://www.ncbi.nlm.nih.gov/pubmed/24991300 http://dx.doi.org/10.3762/bjoc.10.149 |
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