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Quantum Mechanical Analysis of Nonenzymatic Nucleotidyl Transfer Reactions: Kinetic and Thermodynamic Effects of β–γ Bridging Groups of dNTP Substrates
[Image: see text] Rate (k) and equilibrium (K) constants for the reaction of tetrahydrofuranol with a series of Mg(2+) complexes of methyl triphosphate analogues, CH(3)O-P(O(2))-O-P(O(2))-X-PO(3)(4–), X = O, CH(2), CHCH(3), C(CH(3))(2), CFCH(3), CHF, CHCl, CHBr, CFCl, CF(2), CCl(2), and CBr(2), form...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2014
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4081047/ https://www.ncbi.nlm.nih.gov/pubmed/24901652 http://dx.doi.org/10.1021/bi5003713 |