Hydroxyl-Directed Stereoselective Diboration of Alkenes

[Image: see text] An alkoxide-catalyzed directed diboration of alkenyl alcohols is described. This reaction occurs in a stereoselective fashion and is demonstrated with cyclic and acyclic homoallylic and bishomoallylic alcohol substrates. After oxidation, the reaction generates 1,2-diols such that t...

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Detalles Bibliográficos
Autores principales: Blaisdell, Thomas P., Caya, Thomas C., Zhang, Liang, Sanz-Marco, Amparo, Morken, James P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4091278/
https://www.ncbi.nlm.nih.gov/pubmed/24941137
http://dx.doi.org/10.1021/ja504228p

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4091278/
https://www.ncbi.nlm.nih.gov/pubmed/24941137
http://dx.doi.org/10.1021/ja504228p

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