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TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation
TiO(2) semiconducting nanoparticles are known to be photocatalysts of moderate activity due to their high band-gap and high rate of electron-hole recombination. The formation of a shell of carbon around the core of TiO(2), i.e., the formation of TiO(2)@C nanoparticles, is believed to partly alleviat...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Frontiers Media S.A.
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4092372/ https://www.ncbi.nlm.nih.gov/pubmed/25072054 http://dx.doi.org/10.3389/fchem.2014.00047 |
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author | Vasei, Mitra Das, Paramita Cherfouth, Hayet Marsan, Benoît Claverie, Jerome P. |
author_facet | Vasei, Mitra Das, Paramita Cherfouth, Hayet Marsan, Benoît Claverie, Jerome P. |
author_sort | Vasei, Mitra |
collection | PubMed |
description | TiO(2) semiconducting nanoparticles are known to be photocatalysts of moderate activity due to their high band-gap and high rate of electron-hole recombination. The formation of a shell of carbon around the core of TiO(2), i.e., the formation of TiO(2)@C nanoparticles, is believed to partly alleviate these problems. It is usually achieved by a hydrothermal treatment in a presence of a sugar derivative. We present here a novel method for the formation of highly uniform C shell around TiO(2) nanoparticles. For this purpose, TiO(2) nanoparticles were dispersed in water using an oligomeric dispersant prepared by Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization. Then the nanoparticles were engaged into an emulsion polymerization of acrylonitrile, resulting in the formation of a shell of polyacrylonitrile (PAN) around each TiO(2) nanoparticles. Upon pyrolysis, the PAN was transformed into carbon, resulting in the formation of TiO(2)@C nanoparticles. The structure of the resulting particles was elucidated by X-Ray diffraction, FTIR, UV-VIS and Raman spectroscopy as well as TEM microscopy. Preliminary results about the use of the TiO(2)@C particles as photocatalysts for the splitting of water are presented. They indicate that the presence of the C shell is responsible for a significant enhancement of the photocurrent. |
format | Online Article Text |
id | pubmed-4092372 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | Frontiers Media S.A. |
record_format | MEDLINE/PubMed |
spelling | pubmed-40923722014-07-28 TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation Vasei, Mitra Das, Paramita Cherfouth, Hayet Marsan, Benoît Claverie, Jerome P. Front Chem Chemistry TiO(2) semiconducting nanoparticles are known to be photocatalysts of moderate activity due to their high band-gap and high rate of electron-hole recombination. The formation of a shell of carbon around the core of TiO(2), i.e., the formation of TiO(2)@C nanoparticles, is believed to partly alleviate these problems. It is usually achieved by a hydrothermal treatment in a presence of a sugar derivative. We present here a novel method for the formation of highly uniform C shell around TiO(2) nanoparticles. For this purpose, TiO(2) nanoparticles were dispersed in water using an oligomeric dispersant prepared by Reversible Addition-Fragmentation chain Transfer (RAFT) polymerization. Then the nanoparticles were engaged into an emulsion polymerization of acrylonitrile, resulting in the formation of a shell of polyacrylonitrile (PAN) around each TiO(2) nanoparticles. Upon pyrolysis, the PAN was transformed into carbon, resulting in the formation of TiO(2)@C nanoparticles. The structure of the resulting particles was elucidated by X-Ray diffraction, FTIR, UV-VIS and Raman spectroscopy as well as TEM microscopy. Preliminary results about the use of the TiO(2)@C particles as photocatalysts for the splitting of water are presented. They indicate that the presence of the C shell is responsible for a significant enhancement of the photocurrent. Frontiers Media S.A. 2014-07-11 /pmc/articles/PMC4092372/ /pubmed/25072054 http://dx.doi.org/10.3389/fchem.2014.00047 Text en Copyright © 2014 Vasei, Das, Cherfouth, Marsan and Claverie. http://creativecommons.org/licenses/by/3.0/ This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) or licensor are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms. |
spellingShingle | Chemistry Vasei, Mitra Das, Paramita Cherfouth, Hayet Marsan, Benoît Claverie, Jerome P. TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title | TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title_full | TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title_fullStr | TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title_full_unstemmed | TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title_short | TiO(2)@C core-shell nanoparticles formed by polymeric nano-encapsulation |
title_sort | tio(2)@c core-shell nanoparticles formed by polymeric nano-encapsulation |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4092372/ https://www.ncbi.nlm.nih.gov/pubmed/25072054 http://dx.doi.org/10.3389/fchem.2014.00047 |
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