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Effect of ZnO:Cs(2)CO(3) on the performance of organic photovoltaics

We demonstrate a new solution-processed electron transport layer (ETL), zinc oxide doped with cesium carbonate (ZnO:Cs(2)CO(3)), for achieving organic photovoltaics (OPVs) with good operational stability at ambient air. An OPV employing the ZnO:Cs(2)CO(3) ETL exhibits a fill factor of 62%, an open c...

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Detalles Bibliográficos
Autores principales: Kim, Hyeong Pil, Yusoff, Abd Rashid bin Mohd, Lee, Hee Jae, Lee, Seung Joo, Kim, Hyo Min, Seo, Gi Jun, Youn, Jun Ho, Jang, Jin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4099096/
https://www.ncbi.nlm.nih.gov/pubmed/25045340
http://dx.doi.org/10.1186/1556-276X-9-323
Descripción
Sumario:We demonstrate a new solution-processed electron transport layer (ETL), zinc oxide doped with cesium carbonate (ZnO:Cs(2)CO(3)), for achieving organic photovoltaics (OPVs) with good operational stability at ambient air. An OPV employing the ZnO:Cs(2)CO(3) ETL exhibits a fill factor of 62%, an open circuit voltage of 0.90 V, and a short circuit current density of −6.14 mA/cm(2) along with 3.43% power conversion efficiency. The device demonstrated air stability for a period over 4 weeks. In addition, we also studied the device structure dependence on the performance of organic photovoltaics. Thus, we conclude that ZnO:Cs(2)CO(3) ETL could be employed in a suitable architecture to achieve high-performance OPV.