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Type II halogen···halogen contacts are halogen bonds

Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen···halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition.

Detalles Bibliográficos
Autores principales: Metrangolo, Pierangelo, Resnati, Giuseppe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4104972/
https://www.ncbi.nlm.nih.gov/pubmed/25075314
http://dx.doi.org/10.1107/S205225251303491X
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author Metrangolo, Pierangelo
Resnati, Giuseppe
author_facet Metrangolo, Pierangelo
Resnati, Giuseppe
author_sort Metrangolo, Pierangelo
collection PubMed
description Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen···halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition.
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spelling pubmed-41049722014-07-24 Type II halogen···halogen contacts are halogen bonds Metrangolo, Pierangelo Resnati, Giuseppe IUCrJ Scientific Commentaries Cl/Br/I alternative substitutions in a series of dihalophenols indicate that type I and type II halogen···halogen contacts have different chemical nature. Only the latter ones qualify as true halogen bonds, according to the recent IUPAC definition. International Union of Crystallography 2013-12-31 /pmc/articles/PMC4104972/ /pubmed/25075314 http://dx.doi.org/10.1107/S205225251303491X Text en © Metrangolo and Resnati 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Scientific Commentaries
Metrangolo, Pierangelo
Resnati, Giuseppe
Type II halogen···halogen contacts are halogen bonds
title Type II halogen···halogen contacts are halogen bonds
title_full Type II halogen···halogen contacts are halogen bonds
title_fullStr Type II halogen···halogen contacts are halogen bonds
title_full_unstemmed Type II halogen···halogen contacts are halogen bonds
title_short Type II halogen···halogen contacts are halogen bonds
title_sort type ii halogen···halogen contacts are halogen bonds
topic Scientific Commentaries
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4104972/
https://www.ncbi.nlm.nih.gov/pubmed/25075314
http://dx.doi.org/10.1107/S205225251303491X
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