Effect of Allylic Groups on S(N)2 Reactivity

[Image: see text] The activating effects of the benzyl and allyl groups on S(N)2 reactivity are well-known. 6-Chloromethyl-6-methylfulvene, also a primary, allylic halide, reacts 30 times faster with KI/acetone than does benzyl chloride at room temperature. The latter result, as well as new experime...

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Detalles Bibliográficos
Autores principales: Erden, Ihsan, Gronert, Scott, Keeffe, James R., Ma, Jingxiang, Ocal, Nuket, Gärtner, Christian, Soukup, Leah L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2014
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4111211/
https://www.ncbi.nlm.nih.gov/pubmed/24977317
http://dx.doi.org/10.1021/jo501157s

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4111211/
https://www.ncbi.nlm.nih.gov/pubmed/24977317
http://dx.doi.org/10.1021/jo501157s

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