Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex

A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

Detalles Bibliográficos
Autores principales: Gavette, Jesse V., Klug, Christina M., Zakharov, Lev N., Shores, Matthew P., Haley, Michael M., Johnson, Darren W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2014
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4112994/
https://www.ncbi.nlm.nih.gov/pubmed/24854889
http://dx.doi.org/10.1039/c4cc02297a
Descripción
Sumario:A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.

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