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Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4112994/ https://www.ncbi.nlm.nih.gov/pubmed/24854889 http://dx.doi.org/10.1039/c4cc02297a |
| _version_ | 1782328234133684224 |
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| author | Gavette, Jesse V. Klug, Christina M. Zakharov, Lev N. Shores, Matthew P. Haley, Michael M. Johnson, Darren W. |
| author_facet | Gavette, Jesse V. Klug, Christina M. Zakharov, Lev N. Shores, Matthew P. Haley, Michael M. Johnson, Darren W. |
| author_sort | Gavette, Jesse V. |
| collection | PubMed |
| description | A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography. |
| format | Online Article Text |
| id | pubmed-4112994 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | Royal Society of Chemistry |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41129942014-09-10 Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex Gavette, Jesse V. Klug, Christina M. Zakharov, Lev N. Shores, Matthew P. Haley, Michael M. Johnson, Darren W. Chem Commun (Camb) Chemistry A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography. Royal Society of Chemistry 2014-11-07 2014-05-23 /pmc/articles/PMC4112994/ /pubmed/24854889 http://dx.doi.org/10.1039/c4cc02297a Text en This journal is © The Royal Society of Chemistry 2014 http://creativecommons.org/licenses/by-nc/2.0/uk/ This is an Open Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/2.0/uk/) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited. |
| spellingShingle | Chemistry Gavette, Jesse V. Klug, Christina M. Zakharov, Lev N. Shores, Matthew P. Haley, Michael M. Johnson, Darren W. Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex |
| title | Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
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| title_full | Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
|
| title_fullStr | Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
|
| title_full_unstemmed | Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
|
| title_short | Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
|
| title_sort | intramolecular n–h···cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral felcl(2) complex |
| topic | Chemistry |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4112994/ https://www.ncbi.nlm.nih.gov/pubmed/24854889 http://dx.doi.org/10.1039/c4cc02297a |
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