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Intramolecular N–H···Cl hydrogen bonds in the outer coordination sphere of a bipyridyl bisurea-based ligand stabilize a tetrahedral FeLCl(2) complex
A bipyridyl-based anion receptor is utilized as a ligand in a tetrahedral FeCl(2) complex and demonstrates secondary coordination sphere influence through intramolecular hydrogen bonding to the chloride ligands as evidenced by X-ray crystallography.
Autores principales: | Gavette, Jesse V., Klug, Christina M., Zakharov, Lev N., Shores, Matthew P., Haley, Michael M., Johnson, Darren W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4112994/ https://www.ncbi.nlm.nih.gov/pubmed/24854889 http://dx.doi.org/10.1039/c4cc02297a |
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