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2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide

In the title compound, C(27)H(29)BrN(4)O, benzimidazole ring system and the amide moiety are planar [r.m.s. deviations = 0.016 (2) and 0.017 (1) Å, respectively]. The mol­ecule adopts a conformation in which the amide linkage is almost perpendicular to the central ring [dihedral angle = 85.79 (8)°],...

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Autores principales: Prasad, Poonam Rajesh, Das, Shikha, Singh, Harkesh B., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120529/
https://www.ncbi.nlm.nih.gov/pubmed/25161598
http://dx.doi.org/10.1107/S1600536814014433
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author Prasad, Poonam Rajesh
Das, Shikha
Singh, Harkesh B.
Butcher, Ray J.
author_facet Prasad, Poonam Rajesh
Das, Shikha
Singh, Harkesh B.
Butcher, Ray J.
author_sort Prasad, Poonam Rajesh
collection PubMed
description In the title compound, C(27)H(29)BrN(4)O, benzimidazole ring system and the amide moiety are planar [r.m.s. deviations = 0.016 (2) and 0.017 (1) Å, respectively]. The mol­ecule adopts a conformation in which the amide linkage is almost perpendicular to the central ring [dihedral angle = 85.79 (8)°], while the benzimidazole ring system makes a dihedral angle of 70.26 (11)° with the central ring. In the crystal, the mol­ecules form dimers through N—H⋯O hydrogen bonds and C—H⋯O interactions. These dimers are further linked into zigzag ribbons along [201] by weak C—H⋯Br inter­actions. As a result of the bulky nature of the mol­ecule, as evidenced by the large dihedral angles between rings, there is little evidence for any π–π inter­actions.
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spelling pubmed-41205292014-08-26 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide Prasad, Poonam Rajesh Das, Shikha Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(27)H(29)BrN(4)O, benzimidazole ring system and the amide moiety are planar [r.m.s. deviations = 0.016 (2) and 0.017 (1) Å, respectively]. The mol­ecule adopts a conformation in which the amide linkage is almost perpendicular to the central ring [dihedral angle = 85.79 (8)°], while the benzimidazole ring system makes a dihedral angle of 70.26 (11)° with the central ring. In the crystal, the mol­ecules form dimers through N—H⋯O hydrogen bonds and C—H⋯O interactions. These dimers are further linked into zigzag ribbons along [201] by weak C—H⋯Br inter­actions. As a result of the bulky nature of the mol­ecule, as evidenced by the large dihedral angles between rings, there is little evidence for any π–π inter­actions. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120529/ /pubmed/25161598 http://dx.doi.org/10.1107/S1600536814014433 Text en © Prasad et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Prasad, Poonam Rajesh
Das, Shikha
Singh, Harkesh B.
Butcher, Ray J.
2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title_full 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title_fullStr 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title_full_unstemmed 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title_short 2-Bromo-5-tert-butyl-N-methyl-N-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1H-benzimidazol-2-yl)benzamide
title_sort 2-bromo-5-tert-butyl-n-methyl-n-[2-(methyl­amino)­phen­yl]-3-(1-methyl-1h-benzimidazol-2-yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120529/
https://www.ncbi.nlm.nih.gov/pubmed/25161598
http://dx.doi.org/10.1107/S1600536814014433
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