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μ(2)-Acetato-κ(2) O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2) S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate
In the title compound, [Mo(3)(CH(3)COO)(C(4)H(10)O(2)PS(2))(3)S(4)(C(10)H(8)N(2))]·C(4)H(10)O, the complex molecule has a trinuclear incomplete cuboidal structure which is coordinated by three kinds of ligands, namely, diethyl dithiophosphate, acetate and 4,4′-bipyridyl. If Mo—Mo bonds are ignore...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120534/ https://www.ncbi.nlm.nih.gov/pubmed/25161512 http://dx.doi.org/10.1107/S1600536814012501 |
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author | Kawamoto, Keisuke Kinoshita, Isamu |
author_facet | Kawamoto, Keisuke Kinoshita, Isamu |
author_sort | Kawamoto, Keisuke |
collection | PubMed |
description | In the title compound, [Mo(3)(CH(3)COO)(C(4)H(10)O(2)PS(2))(3)S(4)(C(10)H(8)N(2))]·C(4)H(10)O, the complex molecule has a trinuclear incomplete cuboidal structure which is coordinated by three kinds of ligands, namely, diethyl dithiophosphate, acetate and 4,4′-bipyridyl. If Mo—Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octahedral geometry. The Mo—Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo—Mo distances [2.7490 (5) and 2.7566 (5) Å]. One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio. In the crystal, weak C—H⋯O interactions link the trinuclear molecules related by translation in [100] into chains. The crystal packing exhibits short intermolecular S⋯S contacts of 3.1886 (13) Å. In other words, in this crystal packing, a supramolecular structure is constructed by the C—H⋯O and S⋯S interactions. |
format | Online Article Text |
id | pubmed-4120534 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205342014-08-26 μ(2)-Acetato-κ(2) O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2) S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate Kawamoto, Keisuke Kinoshita, Isamu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mo(3)(CH(3)COO)(C(4)H(10)O(2)PS(2))(3)S(4)(C(10)H(8)N(2))]·C(4)H(10)O, the complex molecule has a trinuclear incomplete cuboidal structure which is coordinated by three kinds of ligands, namely, diethyl dithiophosphate, acetate and 4,4′-bipyridyl. If Mo—Mo bonds are ignored, each Mo atom can be considered as six-coordinated in a distorted octahedral geometry. The Mo—Mo distance of 2.6880 (5) Å for two the Mo atoms bridged by the acetate ligand is shorter than the other two Mo—Mo distances [2.7490 (5) and 2.7566 (5) Å]. One ethyl group is disordered between two conformations in a 0.65 (3):0.35 (3) ratio. In the crystal, weak C—H⋯O interactions link the trinuclear molecules related by translation in [100] into chains. The crystal packing exhibits short intermolecular S⋯S contacts of 3.1886 (13) Å. In other words, in this crystal packing, a supramolecular structure is constructed by the C—H⋯O and S⋯S interactions. International Union of Crystallography 2014-06-04 /pmc/articles/PMC4120534/ /pubmed/25161512 http://dx.doi.org/10.1107/S1600536814012501 Text en © Kawamoto and Kinoshita 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kawamoto, Keisuke Kinoshita, Isamu μ(2)-Acetato-κ(2) O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2) S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title | μ(2)-Acetato-κ(2)
O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2)
S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title_full | μ(2)-Acetato-κ(2)
O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2)
S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title_fullStr | μ(2)-Acetato-κ(2)
O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2)
S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title_full_unstemmed | μ(2)-Acetato-κ(2)
O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2)
S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title_short | μ(2)-Acetato-κ(2)
O:O′-(4,4′-bipyridyl-κN)tris(diethyl dithiophosphato-κ(2)
S,S′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(IV) diethyl ether monosolvate |
title_sort | μ(2)-acetato-κ(2)
o:o′-(4,4′-bipyridyl-κn)tris(diethyl dithiophosphato-κ(2)
s,s′)-μ(3)-sulfido-tri-μ(2)-sulfido-trimolybdenum(iv) diethyl ether monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120534/ https://www.ncbi.nlm.nih.gov/pubmed/25161512 http://dx.doi.org/10.1107/S1600536814012501 |
work_keys_str_mv | AT kawamotokeisuke m2acetatok2oo44bipyridylkntrisdiethyldithiophosphatok2ssm3sulfidotrim2sulfidotrimolybdenumivdiethylethermonosolvate AT kinoshitaisamu m2acetatok2oo44bipyridylkntrisdiethyldithiophosphatok2ssm3sulfidotrim2sulfidotrimolybdenumivdiethylethermonosolvate |