2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none

In the title compound, C(10)H(14)Br(4)O(5), synthesized from the meth­oxy Schiff base N-(pyridin-2-ylmeth­yl)meth­oxy­aniline and mol­ecular bromine, the cyclo­hexa­none ring has a chair conformation with one of the four meth­oxy groups equatorially orientated with respect to the carbonyl group and...

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Detalles Bibliográficos
Autores principales: Faizi, Md. Serajul Haque, Mashrai, Ashraf, Shahid, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120536/
https://www.ncbi.nlm.nih.gov/pubmed/25161601
http://dx.doi.org/10.1107/S160053681401472X
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author Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
author_facet Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
author_sort Faizi, Md. Serajul Haque
collection PubMed
description In the title compound, C(10)H(14)Br(4)O(5), synthesized from the meth­oxy Schiff base N-(pyridin-2-ylmeth­yl)meth­oxy­aniline and mol­ecular bromine, the cyclo­hexa­none ring has a chair conformation with one of the four meth­oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated. The C—Br bond lengthsvary from 1.942 (4) to1.964 (4) Å. In the crystal, weak C—H⋯O(carbon­yl) hydrogen-bonding inter­actions generate chains extending along the b-axis direction. Also present in the structure are two short inter­molecular Br⋯O(meth­oxy) inter­actions [3.020 (3) and 3.073 (4) Å].
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spelling pubmed-41205362014-08-26 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none Faizi, Md. Serajul Haque Mashrai, Ashraf Shahid, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(14)Br(4)O(5), synthesized from the meth­oxy Schiff base N-(pyridin-2-ylmeth­yl)meth­oxy­aniline and mol­ecular bromine, the cyclo­hexa­none ring has a chair conformation with one of the four meth­oxy groups equatorially orientated with respect to the carbonyl group and the others axially orientated. The C—Br bond lengthsvary from 1.942 (4) to1.964 (4) Å. In the crystal, weak C—H⋯O(carbon­yl) hydrogen-bonding inter­actions generate chains extending along the b-axis direction. Also present in the structure are two short inter­molecular Br⋯O(meth­oxy) inter­actions [3.020 (3) and 3.073 (4) Å]. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120536/ /pubmed/25161601 http://dx.doi.org/10.1107/S160053681401472X Text en © Faizi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Faizi, Md. Serajul Haque
Mashrai, Ashraf
Shahid, M.
2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title_full 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title_fullStr 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title_full_unstemmed 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title_short 2,2,6,6-Tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
title_sort 2,2,6,6-tetra­bromo-3,4,4,5-tetra­meth­oxy­cyclo­hexa­none
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120536/
https://www.ncbi.nlm.nih.gov/pubmed/25161601
http://dx.doi.org/10.1107/S160053681401472X
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