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Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2) N,O)platinum(II)
The title compound, [Pt(C(10)H(6)NO(2))Cl(C(5)H(11)N)], crystallizes with one molecule in the asymmetric unit. The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxylate O atom of the bidentate quinaldate li...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120542/ https://www.ncbi.nlm.nih.gov/pubmed/25161501 http://dx.doi.org/10.1107/S160053681401191X |
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author | Nguyen Thi Thanh, Chi Nguyen Bich, Ngan Van Meervelt, Luc |
author_facet | Nguyen Thi Thanh, Chi Nguyen Bich, Ngan Van Meervelt, Luc |
author_sort | Nguyen Thi Thanh, Chi |
collection | PubMed |
description | The title compound, [Pt(C(10)H(6)NO(2))Cl(C(5)H(11)N)], crystallizes with one molecule in the asymmetric unit. The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxylate O atom of the bidentate quinaldate ligand and a piperidine N atom. An intramolecular C—H⋯Cl hydrogen bond occurs. In the crystal, molecules are stacked into columns along the c axis by the formation of N—H⋯Cl and C—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-4120542 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205422014-08-26 Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2) N,O)platinum(II) Nguyen Thi Thanh, Chi Nguyen Bich, Ngan Van Meervelt, Luc Acta Crystallogr Sect E Struct Rep Online Research Communications The title compound, [Pt(C(10)H(6)NO(2))Cl(C(5)H(11)N)], crystallizes with one molecule in the asymmetric unit. The Pt(II) cation has a slightly distorted square-planar coordination environment defined by a chloride anion, the quinoline N atom and a carboxylate O atom of the bidentate quinaldate ligand and a piperidine N atom. An intramolecular C—H⋯Cl hydrogen bond occurs. In the crystal, molecules are stacked into columns along the c axis by the formation of N—H⋯Cl and C—H⋯O hydrogen bonds. International Union of Crystallography 2014-06-23 /pmc/articles/PMC4120542/ /pubmed/25161501 http://dx.doi.org/10.1107/S160053681401191X Text en © Nguyen Thi Thanh et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Research Communications Nguyen Thi Thanh, Chi Nguyen Bich, Ngan Van Meervelt, Luc Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2) N,O)platinum(II) |
title | Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2)
N,O)platinum(II) |
title_full | Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2)
N,O)platinum(II) |
title_fullStr | Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2)
N,O)platinum(II) |
title_full_unstemmed | Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2)
N,O)platinum(II) |
title_short | Crystal structure of chlorido(piperidine-κN)(quinoline-2-carboxylato-κ(2)
N,O)platinum(II) |
title_sort | crystal structure of chlorido(piperidine-κn)(quinoline-2-carboxylato-κ(2)
n,o)platinum(ii) |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120542/ https://www.ncbi.nlm.nih.gov/pubmed/25161501 http://dx.doi.org/10.1107/S160053681401191X |
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