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Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea
The title compound, C(23)H(32)N(2)OS, is a thiourea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thiourea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120544/ https://www.ncbi.nlm.nih.gov/pubmed/25161588 http://dx.doi.org/10.1107/S1600536814014214 |
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author | Jeon, Youngeun Kang, Gihaeng Cho, Seonghwa Kim, Tae Ho |
author_facet | Jeon, Youngeun Kang, Gihaeng Cho, Seonghwa Kim, Tae Ho |
author_sort | Jeon, Youngeun |
collection | PubMed |
description | The title compound, C(23)H(32)N(2)OS, is a thiourea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thiourea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N—H⋯S hydrogen bonds link adjacent molecules, forming R (2) (2)(8) inversion dimers that pack into chains along the b-axis direction. |
format | Online Article Text |
id | pubmed-4120544 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205442014-08-26 Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea Jeon, Youngeun Kang, Gihaeng Cho, Seonghwa Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(32)N(2)OS, is a thiourea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thiourea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N—H⋯S hydrogen bonds link adjacent molecules, forming R (2) (2)(8) inversion dimers that pack into chains along the b-axis direction. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120544/ /pubmed/25161588 http://dx.doi.org/10.1107/S1600536814014214 Text en © Jeon et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jeon, Youngeun Kang, Gihaeng Cho, Seonghwa Kim, Tae Ho Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title | Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title_full | Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title_fullStr | Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title_full_unstemmed | Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title_short | Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
title_sort | diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phenoxyphenyl)thiourea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120544/ https://www.ncbi.nlm.nih.gov/pubmed/25161588 http://dx.doi.org/10.1107/S1600536814014214 |
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