Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea

The title compound, C(23)H(32)N(2)OS, is a thio­urea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio­urea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S...

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Detalles Bibliográficos
Autores principales: Jeon, Youngeun, Kang, Gihaeng, Cho, Seonghwa, Kim, Tae Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120544/
https://www.ncbi.nlm.nih.gov/pubmed/25161588
http://dx.doi.org/10.1107/S1600536814014214
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author Jeon, Youngeun
Kang, Gihaeng
Cho, Seonghwa
Kim, Tae Ho
author_facet Jeon, Youngeun
Kang, Gihaeng
Cho, Seonghwa
Kim, Tae Ho
author_sort Jeon, Youngeun
collection PubMed
description The title compound, C(23)H(32)N(2)OS, is a thio­urea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio­urea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N—H⋯S hydrogen bonds link adjacent mol­ecules, forming R (2) (2)(8) inversion dimers that pack into chains along the b-axis direction.
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spelling pubmed-41205442014-08-26 Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea Jeon, Youngeun Kang, Gihaeng Cho, Seonghwa Kim, Tae Ho Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(23)H(32)N(2)OS, is a thio­urea-based insecticide. The dihedral angle between the phenyl ring and the diisopropyl benzene ring plane is 73.18 (6)°, while that between the plane of the thio­urea group and the diisopropyl benzene ring is 86.00 (5)°. Disorder was modelled for the S atom and the two methyl C atoms of the isopropyl group over two sets of sites with an occupancy ratio of 0.742 (4):0.258 (4). In the crystal, N—H⋯S hydrogen bonds link adjacent mol­ecules, forming R (2) (2)(8) inversion dimers that pack into chains along the b-axis direction. International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120544/ /pubmed/25161588 http://dx.doi.org/10.1107/S1600536814014214 Text en © Jeon et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jeon, Youngeun
Kang, Gihaeng
Cho, Seonghwa
Kim, Tae Ho
Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title_full Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title_fullStr Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title_full_unstemmed Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title_short Diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
title_sort diafenthiuron: 1-tert-butyl-3-(2,6-diisopropyl-4-phen­oxy­phen­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120544/
https://www.ncbi.nlm.nih.gov/pubmed/25161588
http://dx.doi.org/10.1107/S1600536814014214
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