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1-[(Cyclohexylidene)amino]-3-(prop-2-en-1-yl)thiourea
The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent molecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thiourea and allyl units. In the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120545/ https://www.ncbi.nlm.nih.gov/pubmed/25161602 http://dx.doi.org/10.1107/S1600536814014834 |
Sumario: | The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent molecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thiourea and allyl units. In the crystal, molecules are connected via N—H⋯N and N—H⋯S hydrogen bonds into chains extending along [110] that are further associated through C—H⋯N interactions into layers parallel to (001). The allyl group in one of the independent molecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6):0.147 (6). |
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