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1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea

The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the...

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Detalles Bibliográficos
Autores principales: Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120545/
https://www.ncbi.nlm.nih.gov/pubmed/25161602
http://dx.doi.org/10.1107/S1600536814014834
Descripción
Sumario:The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the crystal, mol­ecules are connected via N—H⋯N and N—H⋯S hydrogen bonds into chains extending along [110] that are further associated through C—H⋯N inter­actions into layers parallel to (001). The allyl group in one of the independent mol­ecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6):0.147 (6).