1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea

The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the...

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Autores principales: Mohamed, Shaaban K., Mague, Joel T., Akkurt, Mehmet, Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120545/
https://www.ncbi.nlm.nih.gov/pubmed/25161602
http://dx.doi.org/10.1107/S1600536814014834
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author Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
author_facet Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
author_sort Mohamed, Shaaban K.
collection PubMed
description The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the crystal, mol­ecules are connected via N—H⋯N and N—H⋯S hydrogen bonds into chains extending along [110] that are further associated through C—H⋯N inter­actions into layers parallel to (001). The allyl group in one of the independent mol­ecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6):0.147 (6).
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spelling pubmed-41205452014-08-26 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea Mohamed, Shaaban K. Mague, Joel T. Akkurt, Mehmet Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(17)N(3)S, consists of three symmetry-independent mol­ecules with distinctly different conformations, as indicated for example by the C—N—C—C torsion angles of −155.9 (3), 89.9 (3) and 81.1 (4)° along the bond between thio­urea and allyl units. In the crystal, mol­ecules are connected via N—H⋯N and N—H⋯S hydrogen bonds into chains extending along [110] that are further associated through C—H⋯N inter­actions into layers parallel to (001). The allyl group in one of the independent mol­ecules is disordered over two sets of sites with an occupancy ratio of 0.853 (6):0.147 (6). International Union of Crystallography 2014-06-25 /pmc/articles/PMC4120545/ /pubmed/25161602 http://dx.doi.org/10.1107/S1600536814014834 Text en © Mohamed et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohamed, Shaaban K.
Mague, Joel T.
Akkurt, Mehmet
Hassan, Alaa A.
Albayati, Mustafa R.
1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title_full 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title_fullStr 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title_full_unstemmed 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title_short 1-[(Cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
title_sort 1-[(cyclo­hexyl­idene)amino]-3-(prop-2-en-1-yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120545/
https://www.ncbi.nlm.nih.gov/pubmed/25161602
http://dx.doi.org/10.1107/S1600536814014834
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