Octa-μ(3)-selenido-penta­kis­(tri­ethyl­phos­phane-κP)(tri­methyl­aceto­nitrile-κN)-octa­hedro-hexa­rhenium(III) bis­(hexa­fluorido­anti­monate) tri­methyl­aceto­nitrile monosolvate

The crystal structure of the title compound, [Re(6)Se(8){NCC(CH(3))(3)}(Et(3)P)(5)](SbF(6))(2)·NCC(CH(3))(3), contains a face-capped octa­hedral [Re(6)(μ(3)-Se)(8)](2+) cluster core. The pseudo-centrosymmetric [Re(6)Se(8)](2+) cluster core is bonded through the Re atoms to five tri­ethyl­phosphane l...

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Detalles Bibliográficos
Autores principales: Ren, YiXin, Bruck, Andrea M., Szczepura, Lisa F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120548/
https://www.ncbi.nlm.nih.gov/pubmed/25161513
http://dx.doi.org/10.1107/S1600536814011982
Descripción
Sumario:The crystal structure of the title compound, [Re(6)Se(8){NCC(CH(3))(3)}(Et(3)P)(5)](SbF(6))(2)·NCC(CH(3))(3), contains a face-capped octa­hedral [Re(6)(μ(3)-Se)(8)](2+) cluster core. The pseudo-centrosymmetric [Re(6)Se(8)](2+) cluster core is bonded through the Re atoms to five tri­ethyl­phosphane ligands and one tri­methyl­aceto­nitrile ligand. No significant interactions are observed between the cationic cluster, the SbF(6) (−) anions and the trimethylacetonitrile solvent molecule.

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