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Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate
The crystal structure of the title compound, [Re(6)Se(8){NCC(CH(3))(3)}(Et(3)P)(5)](SbF(6))(2)·NCC(CH(3))(3), contains a face-capped octahedral [Re(6)(μ(3)-Se)(8)](2+) cluster core. The pseudo-centrosymmetric [Re(6)Se(8)](2+) cluster core is bonded through the Re atoms to five triethylphosphane l...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120548/ https://www.ncbi.nlm.nih.gov/pubmed/25161513 http://dx.doi.org/10.1107/S1600536814011982 |
| _version_ | 1782329104873291776 |
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| author | Ren, YiXin Bruck, Andrea M. Szczepura, Lisa F. |
| author_facet | Ren, YiXin Bruck, Andrea M. Szczepura, Lisa F. |
| author_sort | Ren, YiXin |
| collection | PubMed |
| description | The crystal structure of the title compound, [Re(6)Se(8){NCC(CH(3))(3)}(Et(3)P)(5)](SbF(6))(2)·NCC(CH(3))(3), contains a face-capped octahedral [Re(6)(μ(3)-Se)(8)](2+) cluster core. The pseudo-centrosymmetric [Re(6)Se(8)](2+) cluster core is bonded through the Re atoms to five triethylphosphane ligands and one trimethylacetonitrile ligand. No significant interactions are observed between the cationic cluster, the SbF(6) (−) anions and the trimethylacetonitrile solvent molecule. |
| format | Online Article Text |
| id | pubmed-4120548 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-41205482014-08-26 Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate Ren, YiXin Bruck, Andrea M. Szczepura, Lisa F. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Re(6)Se(8){NCC(CH(3))(3)}(Et(3)P)(5)](SbF(6))(2)·NCC(CH(3))(3), contains a face-capped octahedral [Re(6)(μ(3)-Se)(8)](2+) cluster core. The pseudo-centrosymmetric [Re(6)Se(8)](2+) cluster core is bonded through the Re atoms to five triethylphosphane ligands and one trimethylacetonitrile ligand. No significant interactions are observed between the cationic cluster, the SbF(6) (−) anions and the trimethylacetonitrile solvent molecule. International Union of Crystallography 2014-06-04 /pmc/articles/PMC4120548/ /pubmed/25161513 http://dx.doi.org/10.1107/S1600536814011982 Text en © Ren et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ren, YiXin Bruck, Andrea M. Szczepura, Lisa F. Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title | Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title_full | Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title_fullStr | Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title_full_unstemmed | Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title_short | Octa-μ(3)-selenido-pentakis(triethylphosphane-κP)(trimethylacetonitrile-κN)-octahedro-hexarhenium(III) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| title_sort | octa-μ(3)-selenido-pentakis(triethylphosphane-κp)(trimethylacetonitrile-κn)-octahedro-hexarhenium(iii) bis(hexafluoridoantimonate) trimethylacetonitrile monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120548/ https://www.ncbi.nlm.nih.gov/pubmed/25161513 http://dx.doi.org/10.1107/S1600536814011982 |
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