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(E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide
The title compound, C(12)H(8)ClFN(2)OS, is a hydrazide derivative adopting an E conformation with an azomethine N=C double bond length of 1.272 (2) Å. The molecular skeleton is approximately planar; the terminal five- and six-membered rings form a dihedral angle of 5.47 (9)°. In the crystal, molec...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120552/ https://www.ncbi.nlm.nih.gov/pubmed/25161546 http://dx.doi.org/10.1107/S1600536814011568 |
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author | Sultan, Sadia Taha, Muhammad Shah, Syed Adnan Ali Yamin, Bohari M. Zaki, Hamizah Mohd |
author_facet | Sultan, Sadia Taha, Muhammad Shah, Syed Adnan Ali Yamin, Bohari M. Zaki, Hamizah Mohd |
author_sort | Sultan, Sadia |
collection | PubMed |
description | The title compound, C(12)H(8)ClFN(2)OS, is a hydrazide derivative adopting an E conformation with an azomethine N=C double bond length of 1.272 (2) Å. The molecular skeleton is approximately planar; the terminal five- and six-membered rings form a dihedral angle of 5.47 (9)°. In the crystal, molecules are linked by N—H⋯O and C—H⋯O hydrogen bonds into zigzag chains propagating in [100]. |
format | Online Article Text |
id | pubmed-4120552 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-41205522014-08-26 (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide Sultan, Sadia Taha, Muhammad Shah, Syed Adnan Ali Yamin, Bohari M. Zaki, Hamizah Mohd Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(8)ClFN(2)OS, is a hydrazide derivative adopting an E conformation with an azomethine N=C double bond length of 1.272 (2) Å. The molecular skeleton is approximately planar; the terminal five- and six-membered rings form a dihedral angle of 5.47 (9)°. In the crystal, molecules are linked by N—H⋯O and C—H⋯O hydrogen bonds into zigzag chains propagating in [100]. International Union of Crystallography 2014-06-04 /pmc/articles/PMC4120552/ /pubmed/25161546 http://dx.doi.org/10.1107/S1600536814011568 Text en © Sultan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sultan, Sadia Taha, Muhammad Shah, Syed Adnan Ali Yamin, Bohari M. Zaki, Hamizah Mohd (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title | (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title_full | (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title_fullStr | (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title_full_unstemmed | (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title_short | (E)-3-Chloro-N′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
title_sort | (e)-3-chloro-n′-(2-fluorobenzylidene)thiophene-2-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120552/ https://www.ncbi.nlm.nih.gov/pubmed/25161546 http://dx.doi.org/10.1107/S1600536814011568 |
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