Cargando…
trans-Bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ(2) N (2),N (3)]bis(methanol-κO)iron(II) bis(perchlorate)
The title compound, [Fe(C(12)H(8)N(4)S)(2)(CH(3)OH)(2)](ClO(4))(2), crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N(4)O(2) octahedral coordination geometry is formed by two N,N′-chelating equatorial 2,5-bis(pyridin...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120561/ https://www.ncbi.nlm.nih.gov/pubmed/25161519 http://dx.doi.org/10.1107/S160053681401277X |
Sumario: | The title compound, [Fe(C(12)H(8)N(4)S)(2)(CH(3)OH)(2)](ClO(4))(2), crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N(4)O(2) octahedral coordination geometry is formed by two N,N′-chelating equatorial 2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole ligands and axially coordinating methanol coligands, resulting in the mononuclear trans-(N (2),N (3),O)(2) coordination mode. The methanol co-ligand is involved in a hydrogen bond to the perchlorate counter-ion. |
---|