trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)

The title compound, [Fe(C(12)H(8)N(4)S)(2)(CH(3)OH)(2)](ClO(4))(2), crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N(4)O(2) octa­hedral coordination geometry is formed by two N,N′-chelating equatorial 2,5-bis­(pyridin...

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Detalles Bibliográficos
Autores principales: Kaase, Dominic, Klingele, Julia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120561/
https://www.ncbi.nlm.nih.gov/pubmed/25161519
http://dx.doi.org/10.1107/S160053681401277X
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author Kaase, Dominic
Klingele, Julia
author_facet Kaase, Dominic
Klingele, Julia
author_sort Kaase, Dominic
collection PubMed
description The title compound, [Fe(C(12)H(8)N(4)S)(2)(CH(3)OH)(2)](ClO(4))(2), crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N(4)O(2) octa­hedral coordination geometry is formed by two N,N′-chelating equatorial 2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole ligands and axially coordinating methanol coligands, resulting in the mononuclear trans-(N (2),N (3),O)(2) coordination mode. The methanol co-ligand is involved in a hydrogen bond to the perchlorate counter-ion.
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spelling pubmed-41205612014-08-26 trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate) Kaase, Dominic Klingele, Julia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(12)H(8)N(4)S)(2)(CH(3)OH)(2)](ClO(4))(2), crystallized in the solvent-free form from a methanol solution. The Fe(II) ion is located on a centre of inversion. The distorted N(4)O(2) octa­hedral coordination geometry is formed by two N,N′-chelating equatorial 2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole ligands and axially coordinating methanol coligands, resulting in the mononuclear trans-(N (2),N (3),O)(2) coordination mode. The methanol co-ligand is involved in a hydrogen bond to the perchlorate counter-ion. International Union of Crystallography 2014-06-07 /pmc/articles/PMC4120561/ /pubmed/25161519 http://dx.doi.org/10.1107/S160053681401277X Text en © Kaase and Klingele 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kaase, Dominic
Klingele, Julia
trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title_full trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title_fullStr trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title_full_unstemmed trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title_short trans-Bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) N (2),N (3)]bis­(methanol-κO)iron(II) bis­(perchlorate)
title_sort trans-bis[2,5-bis­(pyridin-2-yl)-1,3,4-thia­diazole-κ(2) n (2),n (3)]bis­(methanol-κo)iron(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120561/
https://www.ncbi.nlm.nih.gov/pubmed/25161519
http://dx.doi.org/10.1107/S160053681401277X
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AT klingelejulia transbis25bispyridin2yl134thiadiazolek2n2n3bismethanolkoironiibisperchlorate

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