2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate

In the cation of the title salt, C(10)H(10)N(3) (+)·C(6)H(2)N(3)O(7) (−), the pyridine and pyridinium rings are linked by an intra­molecular N—H⋯N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked...

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Detalles Bibliográficos
Autores principales: Ohui, Kateryna A., Golenya, Irina A., Bokach, Nadezhda A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120562/
https://www.ncbi.nlm.nih.gov/pubmed/25161565
http://dx.doi.org/10.1107/S1600536814012835
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author Ohui, Kateryna A.
Golenya, Irina A.
Bokach, Nadezhda A.
author_facet Ohui, Kateryna A.
Golenya, Irina A.
Bokach, Nadezhda A.
author_sort Ohui, Kateryna A.
collection PubMed
description In the cation of the title salt, C(10)H(10)N(3) (+)·C(6)H(2)N(3)O(7) (−), the pyridine and pyridinium rings are linked by an intra­molecular N—H⋯N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked through N—H⋯O hydrogen bonds, forming supra­molecular chains propagating along the c-axis direction. π–π stacking is observed between neighbouring chains, the centroid–centroid distances being 3.7638 (11) (between pyridinium rings) and 3.5331 (11) Å (between benzene rings).
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spelling pubmed-41205622014-08-26 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate Ohui, Kateryna A. Golenya, Irina A. Bokach, Nadezhda A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title salt, C(10)H(10)N(3) (+)·C(6)H(2)N(3)O(7) (−), the pyridine and pyridinium rings are linked by an intra­molecular N—H⋯N hydrogen bond and are approximately coplanar, with a dihedral angle between their planes of 4.24 (6)°. In the crystal, the cations and anions are linked through N—H⋯O hydrogen bonds, forming supra­molecular chains propagating along the c-axis direction. π–π stacking is observed between neighbouring chains, the centroid–centroid distances being 3.7638 (11) (between pyridinium rings) and 3.5331 (11) Å (between benzene rings). International Union of Crystallography 2014-06-14 /pmc/articles/PMC4120562/ /pubmed/25161565 http://dx.doi.org/10.1107/S1600536814012835 Text en © Ohui et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ohui, Kateryna A.
Golenya, Irina A.
Bokach, Nadezhda A.
2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title_full 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title_fullStr 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title_full_unstemmed 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title_short 2-[(Pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
title_sort 2-[(pyridin-2-yl)amino]­pyridinium 2,4,6-tri­nitro­phenolate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4120562/
https://www.ncbi.nlm.nih.gov/pubmed/25161565
http://dx.doi.org/10.1107/S1600536814012835
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AT bokachnadezhdaa 2pyridin2ylaminopyridinium246trinitrophenolate

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